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Scope of controlled synthesis via chain-growth condensation polymerization: from aromatic polyamides to [small pi]-conjugated polymers

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Chem. Commun., 2013, 49,8281-8310
DOI: 10.1039/C3CC43603A, Feature Article
Tsutomu Yokozawa, Yoshihiro Ohta
The mechanism of condensation polymerization of some monomers has been converted from step-growth to chain-growth by means of activation of the polymer end group, either due to a difference of substituent effect between the monomer and the polymer, or by successive intramolecular transfer of catalyst to the polymer end.
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