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Stereoselective metal-free catalytic synthesis of chiral trifluoromethyl aryl and alkyl amines

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Chem. Commun., 2013, 49,8365-8367
DOI: 10.1039/C3CC43821J, Communication
Andrea Genoni, Maurizio Benaglia, Elisabetta Massolo, Sergio Rossi
The enantioselective catalytic HSiCl3-mediated reduction led to trifluoromethyl aryl and alkyl amines typically in >90% yield and up to 98% e.e.
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