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Enhanced [small pi]-frustration in carbo-benzenic chromophores

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Chem. Commun., 2013, 49,8374-8376
DOI: 10.1039/C3CC43204A, Communication
Iaroslav Baglai, Valerie Maraval, Christian Bijani, Nathalie Saffon-Merceron, Zoia Voitenko, Yulian M. Volovenko, Remi Chauvin
The high [small pi]-donation of two enamine substituents remains compatible with a carbo-benzene core, but dramatically enhances the nucleophilic character of C[triple bond, length as m-dash]C and C[double bond, length as m-dash]C linkers.
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