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Anionic polymerization and polyhomologation: an ideal combination to synthesize polyethylene-based block copolymers

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Chem. Commun., 2013, Advance Article
DOI: 10.1039/C3CC44928A, Communication
Hefeng Zhang, Nazeeha Alkayal, Yves Gnanou, Nikos Hadjichristidis
A novel one-pot methodology combining anionic polymerization and polyhomologation, through a "bridge" molecule (BF3OEt2), was developed for the synthesis of polyethylene (PE)-based block copolymers.
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