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Development of an expedient intramolecular Pauson-Khand reaction approach to stereoselectively construct the trans-decalin with a C1 quaternary chiral center

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Chem. Commun., 2013, Advance Article
DOI: 10.1039/C3CC45170D, Communication
Li-Li Shi, Hong-Juan Shen, Li-Chao Fang, Jun Huang, Chuang-Chuang Li, Zhen Yang
Stereoselective synthesis of the trans-decalin subunit with a defined C1 quaternary chiral center has been achieved by the Pauson-Khand reaction (PKR) as a key step.
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