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Dramatic tuning of ligand donor properties in (Ttz)CuCO through remote binding of H+ (Ttz = hydrotris(triazolyl)borate)

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Chem. Commun., 2013, Advance Article
DOI: 10.1039/C3CC00036B, Communication
Natalie A. Dixon, Ashley B. McQuarters, Jodi S. Kraus, Jonathan B. Soffer, Nicolai Lehnert, Reinhard Schweitzer-Stenner, Elizabeth T. Papish
Acids change the donor properties of Ttz ligands in copper(I) complexes, and protonation thus creates more electrophilic catalysts for C-H activation.
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