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Water-soluble C60- and C70-PVP polymers for biomaterials with efficient 1O2 generation

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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC45501G, Communication
Sean Oriana, Safwan Aroua, Justus Oliver Butz Sollner, Xialjing Ma, Yuko Iwamoto, Yoko Yamakoshi
Highly water-soluble fullerene polymers were successfully prepared by a simple direct free-radical copolymerization of N-vinylpyrrolidone and intact C60 or C70 as a radical-capping agent. By the use of AIBN as a radical initiator, the polymers (C60- or C70-PVP) with significantly high molecular weight ([similar]30 kDa) and with efficient 1O2 generation were obtained.
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