A Lewis acid catalytic core sandwiched by inorganic polyoxoanion caps: selective H2O2-based oxidations with [AlIII4(H2O)10([small beta]-XW9O33H)2]6- (X = AsIII, SbIII)

Chem. Commun., 2013, 49,7914-7916
DOI: 10.1039/C3CC44077J, Communication

Mauro Carraro, Bassem S. Bassil, Antonio Soraru, Serena Berardi, Andreas Suchopar, Ulrich Kortz, Marcella Bonchio
Selectivity is served! A tetranuclear Al(III) array is sandwiched by polyoxotungstate ligands to trigger the chemoselective oxidation of allylic alcohols.
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