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П-conjugated PolyHIPEs as Highly Efficient and Reusable Heterogeneous Photosensitizers

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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC45597A, Communication
Kai Zhang, Zuzana Vobecka, Klaus Tauer, Markus Antonietti, Filipe Vilela
П-conjugated microporous polyHIPEs are synthesized via Suzuki cross-coupling. The polymeric backbone consists of electron donor and acceptor moieties with suitable energetic characteristics to promote an efficient photosensitizing ability for the activation of singlet oxygen, showing an extraordinary high stability. The reaction can be carried out in a continuous flow reaction set-up, realizing complete conversion of [small alpha]-terpinene into ascaridole.
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