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Iodine recycling via 1,3-migration in iodoindoles under metal catalysis

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Chem. Commun., 2013, 49,7779-7781
DOI: 10.1039/C3CC44073G, Communication
Benito Alcaide, Pedro Almendros, Jose M. Alonso, Sara Cembellin, Israel Fernandez, Teresa Martinez del Campo, M. Rosario Torres
3-Phenoxy-(indol-2-yl) allenes were transformed into 1-oxygenated carbazoles via gold catalysis, whereas 3-iodo-(indol-2-yl) allenes under gold- or palladium catalysis afforded 3-iodocarbazoles through rare recycling of halogen groups via 1,3-halogen migration.
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