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Atroposelective [2+2+2] cycloadditions catalyzed by a rhodium(I)-chiral phosphate system

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Chem. Commun., 2013, 49,7833-7835
DOI: 10.1039/C3CC43188F, Communication
Mylene Auge, Marion Barbazanges, Anh Tuan Tran, Antoine Simonneau, Paulin Elley, Hani Amouri, Corinne Aubert, Louis Fensterbank, Vincent Gandon, Max Malacria, Jamal Moussa, Cyril Ollivier
Enantioselective cationic Rh(I)-catalyzed [2+2+2] cycloaddition reactions between diynes and isocyanates relying on the chiral anion strategy have been devised.
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