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Dimerization of Cyclopropenes to Bifurans with Tandem Metal Relay Catalysis

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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC44762F, Communication
Chuanling Song, Di Sun, Xianglong Peng, Jing Bai, Rongyi Zhang, Shengzhen Hou, Jian Wu Wang, Zhenghu Xu
An efficient synthesis of bifurans via dimerization of cyclopropenes has been successfully developed with copper-promoted cycloisomerization and palladium-catalyzed dimerization cascade. These novel bifuran structures possess interesting optoelectronic properties.
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