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Angular dependence of the exchange interaction in fluoride-bridged GdIII-CrIII complexes

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Chem. Commun., 2013, Advance Article
DOI: 10.1039/C3CC42552E, Communication
Saurabh Kumar Singh, Kasper S. Pedersen, Marc Sigrist, Christian Aa. Thuesen, Magnus Schau-Magnussen, Hannu Mutka, Stergios Piligkos, Hogni Weihe, Gopalan Rajaraman, Jesper Bendix
Angular dependence of magnetic couplings in Cr(III)-Gd(III) with unsupported fluoride bridges is modeled computationally. A change from anti- to ferromagnetic coupling is predicted for significantly bent bridges.
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