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n[rightward arrow][small pi]* interactions in poly(lactic acid) suggest a role in protein folding

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Chem. Commun., 2013, 49,7699-7701
DOI: 10.1039/C3CC44317E, Communication
Robert W. Newberry, Ronald T. Raines
Poly(lactic acid) (PLA) is a depsipeptide analog of polyalanine. Its helical structure resembles a polyproline II helix. Analogous n[rightward arrow][small pi]* interactions between backbone carbonyl groups stabilize both structures.
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