Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC45302B, Communication
DOI: 10.1039/C3CC45302B, Communication
Shohei Saita, Yuki Kohno, Nobuhumi Nakamura, Hiroyuki Ohno
Polar ionic liquids (ILs) showing phase separation with water were prepared by mixing different types of hydrophilic and polar amino acid ionic liquids (AAILs). When water soluble trihexyl-n-octylphosphonium L-lysinate ([P6668][Lys]) and trihexyl-n-octylphosphonium L-aspartate ([P6668][Asp]) were mixed, it showed phase separation with water due to lowering of the hydration degree attributed to the interaction between side chains of the amino acid anions.
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Polar ionic liquids (ILs) showing phase separation with water were prepared by mixing different types of hydrophilic and polar amino acid ionic liquids (AAILs). When water soluble trihexyl-n-octylphosphonium L-lysinate ([P6668][Lys]) and trihexyl-n-octylphosphonium L-aspartate ([P6668][Asp]) were mixed, it showed phase separation with water due to lowering of the hydration degree attributed to the interaction between side chains of the amino acid anions.
The content of this RSS Feed (c) The Royal Society of Chemistry