Gate effects in a hexagonal zinc-imidazolate-4-amide-5-imidate framework with flexible methoxy substituents and CO2 selectivity

Chem. Commun., 2013, 49,7599-7601
DOI: 10.1039/C3CC42156B, Communication

Suvendu Sekhar Mondal, Asamanjoy Bhunia, Igor A. Baburin, Christian Jager, Alexandra Kelling, Uwe Schilde, Gotthard Seifert, Christoph Janiak, Hans-Jurgen Holdt
IFP-7 is generated, having flexible methoxy groups, which act as molecular gates for guest molecules. This allows highly selective CO₂ sorption over N₂ and CH₄ gases.
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