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Allylic C-H alkylation with a CF3-containing nucleophile

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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC43120G, Communication
Lun Li, Qing-Yun Chen, Yong Guo
Allylic C-H alkylations of allylarenes with dimethyl 2-trifluoromethylmalonate were successfully developed. The reactions were carried out at room temperature in presence of catalytic amount of Pd(OAc)2/Ph3P and stoichiometric amount of 2,6-dimethylbenzoquinone.
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