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Oximate metal complexes breaking the limiting esterolytic reactivity of oximate anions

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Chem. Commun., 2013, Advance Article
DOI: 10.1039/C3CC43944E, Communication
Paola Gomez-Tagle, Jose Carlos Lugo-Gonzalez, Anatoly K. Yatsimirsky
The coordination of oximes to metal ions can remove the "solvational imbalance" around the oximate nucleophile and this allows one to bring the esterolytic reactivity of oximates to an unprecedentedly high level, comparable with that for the most powerful biological catalysts.
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