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Ln[N(SiMe3)2]3-catalyzed cycloaddition of terminal alkynes to azides leading to 1,5-disubstituted 1,2,3-triazoles: new mechanistic features

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Chem. Commun., 2013, Advance Article
DOI: 10.1039/C3CC42534G, Communication
Longcheng Hong, Weijia Lin, Fangjun Zhang, Ruiting Liu, Xigeng Zhou
We report the first example of rare earth metal-catalyzed cycloaddition of terminal alkynes to azides resulting in the formation of 1,5-disubstituted 1,2,3-triazoles.
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